Publication detail

Metal-organic framework nanopesticide carrier for accurate pesticide delivery and decrement of groundwater pollution

Ly, Nguyen Hoang Nguyen, Nguyen Binh Tran, Huynh Nhu Hoang, Thi Thuy Hang Joo, Sang-Woo Vasseghian, Yasser Kamyab, Hesam Chelliapan, Shreeshivadasan Klemes, Jiri Jaromir

English title

Metal-organic framework nanopesticide carrier for accurate pesticide delivery and decrement of groundwater pollution

Type

WoS Article

Language

en

Original abstract

The motivation of the present study was a synthesis of the nanocomposites of UiO-66@ZnO/Biochar to embed carbendazim (CBZ) pesticide inside its porous structures for smart spraying and cleaner production. CBZ@UiO-66@ZnO/Biochar had the purpose of not only smart spraying to avoid releasing a large amount of CBZ into the groundwater but also of accurately delivering the CBZ pesticide to the desired grass/plant. High-resolution electron microscopy was introduced to characterise the morphologies of prepared composites with spatial elemental distribution mapping. X-ray diffraction (XRD) patterns and micro-Raman spectroscopy were employed for the crystal structures of UiO-66@ZnO. Spectral UV-Vis and Fourier transform-infrared (FT-IR) tools were utilized to estimate the UiO-66@ZnO/Biochar-based adsorption and release of CBZ into the dimethyl sulfoxide (DMSO)-water mixture. Our results indicated that the adsorption capacities of CBZ into the DMSO-water mixture onto UiO-66@ZnO and UiO-66@ZnO/Biochar nanocomposites were obtained at 68.8% and 72.6%. The half-life of photodegradation rate constants for CBZ@UiO-66@ZnO/Biochar was found to be 12.3 times longer than that of free CBZ. Notably, CBZ@UiO-66@ZnO/Biochar inhibitory concentration 50% (IC50) determination was estimated at 73.8 mu g/L and 209 mu g/L for Fusarium oxysporum and Aspergillus niger. This work provides a comprehensive experimental scheme for the chemisorption process of CBZ onto the UiO-66@ZnO/Biochar composite materials and the nanopesticide applications in sustainable agriculture towards cleaner productions.

Keywords in English

Biochar; Carbendazim; Cleaner production; Sustainable agriculture; UiO-66; ZnO

Released

2023-05-20

Publisher

ELSEVIER SCI LTDTHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND

Location

ELSEVIER SCI LTDTHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND

ISSN

0959-6526

Journal

Journal of Cleaner Production

Number

402

Pages count

10

BIBTEX


@article{BUT187517,
  author="Ly, Nguyen Hoang and Nguyen, Nguyen Binh and Tran, Huynh Nhu and Hoang, Thi Thuy Hang and Joo, Sang-Woo and Vasseghian, Yasser and Kamyab, Hesam and Chelliapan, Shreeshivadasan and Klemes, Jiri Jaromir",
  title="Metal-organic framework nanopesticide carrier for accurate pesticide delivery and decrement of groundwater pollution",
  journal="Journal of Cleaner Production",
  year="2023",
  number="402",
  pages="10",
  doi="10.1016/j.jclepro.2023.136809",
  issn="0959-6526",
  url="https://www.sciencedirect.com/science/article/pii/S0959652623009678?via%3Dihub"
}