Detail publikace

Adsorption sites and ligand effect for CO on an alloy surface: a direct view

GAUTHIER, Y. BUŠ, V. SCHMID, M. PADOVANI, S. LUNDGREN, E. VARGA, P. KRESSE, G. REDINGER, J.

Anglický název

Adsorption sites and ligand effect for CO on an alloy surface: a direct view

Typ

Článek recenzovaný mimo WoS a Scopus

Jazyk

en

Originální abstrakt

CO adsorption on a PtCo(111) surface was studied by scanning tunneling microscopy. Comparison of images with chemical contrast of Pt and Co and images. showing the CO molecules indicates that CO resides exclusively on top of Pt sites and never on Co. CO bonding is highly sensitive to the chemical environment. The probability to find CO on a Pt atom increases drastically with the number of its Co nearest neighbors. Ab initio calculations show that this ligand effect is due to different positions of the center of the Pt d band.

Vydáno

2001-07-16

ISSN

0031-9007

Časopis

Physical Review Letters

Ročník

87

Číslo

3

Strany od–do

036103–

Počet stran

4

BIBTEX


@article{BUT40578,
  author="Y. {Gauthier} and Vladan {Buš} and Michael {Schmid} and S. {Padovani} and E. {Lundgren} and P. {Varga} and G. {Kresse} and J. {Redinger}",
  title="Adsorption sites and ligand effect for CO on an alloy surface: a direct view",
  journal="Physical Review Letters",
  year="2001",
  volume="87",
  number="3",
  pages="4",
  issn="0031-9007"
}